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What are Concrete Admixtures?

Ingredients other than cement, water, and aggregates that impart a specific quality to either plastic (fresh) mix or the hardened concrete (ASTM C496) is called concrete admixture.

Why use Concrete Admixtures?

1. Reduce cost of concrete construction

2. Achieve specific concrete properties more effectively

3. Ensure quality of concrete during mixing, transporting, placing, and curing in adverse weather condition

4. Overcome emergencies during operations

Classification of concrete admixtures:

1. Air entrainers

2. Water reducers

3. High-range water reducers-superplasticizers

4. Retarders

5. Accelerators

6. Fine minerals

7. Specialty admixtures

concrete-admixtures

Air entraining concrete admixture:

Air entraining concrete admixtures produce tiny air bubbles in the hardened concrete to provide space for the water to expand upon freezing.

How do they work?

They are anionic (water hating) agents that form tough, elastic, air filled bubbles. These bubbles reduce stresses caused by movement or freezing of water. They provide more volume for expansion and shorter flow path.

Benefits of air entraining admixture:

  • Increases workability of fresh concrete
  • Increased durability; Better resistance to freeze thaw cycles, de-icers, salts, sulfates, and alkali-silica reactivity

Difficulties:

  • Decreases strength
  • Effect can be reduced in moderate strength concrete by lowering water cement ratio and increasing cement factor

Composition of Air Entrainers:

  • Salt of wood resins (Vinsol resin)
  • Synthetic detergents
  • Salts of sulfonated lignin (by product of paper production)
  • Salts of petroleum acids
  • Salts of proteinaceous material
  • Fatty and resinous acids
  • Alkylbenzene sulfonates
  • Salts of sulfonated hydrocarbons

Usually liquid meets ASTM C260 specifications.

Water Reducing concrete admixture:

Water reducers can result in 3 things:

1. Increased slump at constant w/c

2. Increased strength, by lowering the water content

3. Reduced cost of the cement

How do they do this?

Water reducers increase the mobility of the cement particles in the plastic mix, allowing same workability to be achieved at lower water contents.

Superplasticizers:

Superplasticizers are “high-range” water reducers. Superplasticizers are used when placing:

1. Thin sections or around tightly spaced reinforcing steel

2. concrete underwater

3. concrete by pumping

4. consolidating the concrete is difficult

Note: When super plasticizers are used, the fresh concrete stays workable for only a short period of time (30 min to 60 min), which is why they are usually added at the site

Retarding concrete admixture:

Used to delay the initial set of concrete. Why do we use them?

1. To offset the effect of hot weather

2. Allow for unusual placement or long haul distances

3. Provide time for special finishes

Possible adverse effects of retarders

1. Reduce early age strength

2. Reduction of time between initial and final set

Possible advantages of retarders

1. Air entrainment

2. Increased workability

3. Reduction of time between initial and final set

Note: The use of retarders must be evaluated experimentally before incorporation in mix design

Accelerating concrete admixture:

Used to reduce the time required to develop final strength characteristics in concrete

Possible reasons for using accelerators:

1. Reduce the amount of time before finishing operations begin

2. Reduce curing time

3. Increase rate of strength gain

4. Plug leaks under hydraulic pressure efficiently

5. Offset effect of cold weather

Calcium Chloride is the most widely used accelerator. Initial and final set times reduced

CaCl2 by weight

Initial Set Time in Hrs.

0%

6

1%

3

2%

2

The PCA (Portland Cement Association) recommends against using calcium chloride when:

1. concrete is prestressed

2. concrete contains embedded aluminum such as conduits

3. concrete is subjected to alkali-aggregate reaction

4. concrete is in contact with water or soils containing sulfates

5. concrete is placed during hot weather

6. Mass application of concrete

Alternatives to CaCl2

1. high early strength cement (type III)

2. increase cement content

3. cure at higher temperature (if feasible)

4. triethanolamine, sodium thiocyanate, calcium formate, calcium nitrite, or calcium nitrate

Fine Minerals as concrete admixtures:

Fine mineral admixtures added in large amounts (20% to 100% of cement weight) to improve the characteristics of plastic and hardened concrete. Classification based on chemical and physical properties

1. Cementitious

  • Have hydraulic cementing properties Example: blast furnace slag, natural cement and hydraulic hydrated lime

2. Pozzolanic

  • Siliceous and aluminous material
  • Little or no cementitious value
  • In presence of moisture, will react with calcium hydroxide to form compounds with cementitious properties 15% of PC weight is hydrated lime. Addition of pozzolan could make the hydrated lime into a cementitious material

Classification of fly ash and natural pozzolans

  • Class N: Raw or calcinated natural pozzolans, e.g. diatomaceous earths, opaline cherts and shales, ruffs and volcanic ashes, & some calcined clays and shales
  • Class F: Fly ash with pozzolan properties
    Class C: Fly ash with pozzolan and cementitious properties

Fly ash is the most commonly used pozzolan in civil engineering structures

Special concrete admixtures:

Other admixtures are available to improve concrete quality in a number of ways, such as workability agents, bonding agents, etc.

Table: Effect of Mineral Admixtures on Fresh Concrete

Quality Measure

Effect

Water Requirements

Fly ash reduces water requirements

Silica fume increases water requirements

Air Content

Fly ash and silica fume reduce air content

It can be avoided by increasing air entrainer.

Workability

Fly ash, ground slag, and inert materials generally increases workability. Silica fume reduces workability; compensate by using super-plasticizers.

Hydration

Fly ash reduces heat of hydration. Silica fume may not affect, but superplasticizers used with silica fume can increase heat.

Set Time

Fly ash, natural pozzolans, and blast furnace slag increase set time; Can compensate by using accelerator.

Table: Effect of Mineral Admixtures on Hardened Concrete

Quality Measure

Effect

Strength

Fly ash increases the ultimate strength but reduces rate of strength gain. Silica fume has less effect on rate of strength gain than pozzolans.

Drying shrinkage and creep

Low concentrations usually have single effect. High concentrations of ground slag or fly ash may increase shrinkage. Silica fume may reduce shrinkage.

Permeability and absorption

Generally reduced permeability and absorption.

Silica fume is especially effective.

Alkali-aggregate reactivity

Generally reduced reactivity, extend of improvement depends on type of admixture.

Sulfate resistance

Improved due to reduced permeability.